Chemical flushing and cleaning of boilers completely remove scale and other deposits. Chemical flushing of boilers: a description of the available means and rules for execution

Timely technical inspection and maintenance of boiler equipment will always contribute to its uninterrupted and stable operation.

One of the important maintenance works is the cleaning and washing of boilers.

In this article we will describe in detail all the nuances and aspects of this type of work.

The essence of the procedure

Internal walls of pipes before and after chemical processing It's no secret that when operating boiler equipment on internal surfaces scale and various kinds of chemical pollution settle. This, in turn, complicates the operation of the boiler system.

The scope of work, which includes cleaning and removing unnecessary deposits, is precisely called the chemical washing of the boiler.

It is also worth noting that flushing is a relatively inexpensive cleaning method that results in maximum efficiency. (You can read about flushing the heating boiler from scale).

Advantages

Chemical flushing of boilers contributes to the following positive aspects:

Such improvements confirm once again that flushing is really effective and rational method boiler system cleaning.

Sequence of work

Flushing of boiler equipment should take place in a strictly defined order, the main stages of which are the following important points:

In fact, all stages of work do not pose any particular technical difficulties, but for a better understanding, it is worth dwelling in more detail on which devices are used to carry out the entire washing process.

Equipment for cleaning boiler systems

As mentioned above, the entire process of chemical washing is carried out using a special device called a booster.

The booster consists of the following elements:


It should be noted that the booster is a unique device of its kind, which greatly facilitates the washing of boiler equipment.

Materials used

An important aspect of washing the boiler unit is the question of the use of various acidic substances.

There are the following types of acids with which boiler equipment is cleaned:

  1. Adipic acid. This substance is diluted with water in a certain proportion, and is directly fed into the boiler with the help of a booster. Carbon dioxide, when interacting with dirt and scale, dissolves them, and then turns into a precipitate, which is subsequently washed out under pressure technical water. Most the best option the use of a solution with adipic acid will be for chemical washing of domestic boilers for heating.
  2. Lemon acid. This type of acidic substance greatly simplifies the cleaning of the boiler, as it can be added directly to the reagent that circulates in process water.
  3. Sulfamic acid. After the circulation of this reagent in the boiler equipment, it is necessary to thoroughly rinse the system and then dry it. This type of acid effectively cleans the interior surfaces of steam boilers.
  4. Hydrochloric acid. The concentration of the solution of this aggressive substance directly depends on the thickness of the contaminated scale. If the thickness of the deposits is 1 mm, then, accordingly, there should be a 1% solution. In other cases, the concentration of the solution does not increase, and the boiler is flushed several times. Hydrochloric acid is optimally suited for cleaning waste heat boilers.
  5. Gel. This type of substance does not belong to acidic environments, however, it dissolves oil-based pollutants quite well. The main condition for the use of a gel substance is a thorough flushing of the boiler equipment with technical fluid.

After reviewing the characteristics of chemicals for cleaning the boiler, we can conclude that all types of substances used are aggressive, so you must take precautions when working with them.

Safety regulations

When working with substances for chemical washing of boilers, it is necessary to observe a number of the following recommendations:

In this article, we have introduced you in detail to all aspects of chemical washing of boiler equipment. Taking them into account, you can easily cope with the dry cleaning of boilers of any modification.

Watch the video in which experts demonstrate competent chemical washing of the boiler:

  • To achieve the optimal result of boiler cleaning, complex hydrochemical and hydrodynamic, hydropower and hydroabrasive cleaning technologies are used, which are currently the most effective.
  • When carrying out the work, high-quality powerful equipment is used, including hydrodynamic machines with a pressure of up to 1500 bar, installations for cleaning the internal surfaces of pipes using soft abrasive materials, hydraulic impulse equipment for cleaning pipes with diameters from 10 to 100 mm, as well as pumping stations capacity up to 200m3/h to ensure the circulation of reagents.
  • The company has implemented a quality management system ISO 9001-2008, which guarantees the accuracy of all business processes.
  • The company has implemented the environmental management system ISO 14001:2004.
  • The company has implemented the occupational safety and health management system OHAS 18001:2007
  • For the most effective cleaning by the hydrochemical method, reagents and corrosion inhibitors with the highest efficiency are used.
  • The company is a design organization and has a SRO permit for the design of works that affect the safety of facilities capital construction, for each type of work, a project for the production of work or technological regulations is developed.
  • Professional specialists have all the necessary certificates and carry out work strictly according to technological maps.
  • The VekFort company is responsible for the structural materials of boiler equipment and excludes their damage.
  • The company employs qualified inspectors whose duty is to conduct internal control of the work performed before handing it over to the customer.

The hydrochemical cleaning method is the process of cleaning the internal surfaces of thermal and heat exchange equipment and systems from scale-corrosive deposits, by circulating working solutions of special technical detergents, mineral or organic acids with special additives along the circuit. The flushing process dissolves and removes deposits without damaging the underlying structural material. The technology is used for cleaning heating systems, non-separable boilers and heat exchangers.

Hydro-chemical flushing is very effective in removing deposits in thermal and heat exchange systems, including pipelines, as it completely dissolves and removes all deposits from the system. Deposits, as a rule, are multicomponent solid layers, which consist of oxides of iron and carbonates, phosphates, sulfates, calcium oxide, magnesium, they create a large thermal resistance heat flow, which leads to a decrease in the temperature of the coolant and a decrease in the thermal conductivity of the heating system.

Hydrochemical cleaning of the internal surfaces of hot water boilers must be carried out on a regular basis, since the formation of scale-corrosive deposits on the internal surfaces of the water path of the boiler during its operation leads to a significant decrease in its operating efficiency and the entire associated system. This leads to a decrease and destabilization of the heat exchange of the system, equipment failures occur, damage to pipelines and increase fuel consumption.

Periodic hydrochemical cleaning of hot water boilers avoids all negative consequences associated with the formation of solid scale-corrosive deposits!

The amount of deposits on the internal surfaces of the boiler must be determined after each heating season based on the methodology for determining the density and composition of deposits given in RD 153-34.1-37.306-2001.

We carry out works on cleaning water boilers from scale-corrosion deposits in the following order:

1. Inspection of the state of the hot water boiler.

The inspection of the state of the boiler is carried out jointly with representatives of the operation service. Before starting work, it is necessary to cut a pipe sample, preferably a section of the outer coil of the convective part, as the most determining resistance, in order to determine the degree of clogging with deposits. The survey can be carried out both visually and laboratory, by analyzing the full composition of the sediments. The method of laboratory examination is carried out in specialized laboratories.

2. Washing the internal surfaces of the boiler network water.

3. Installation of the cleaning circuit.

The boiler is turned off and fittings are inserted to connect the equipment and create a flushing circulation circuit.
For organization technological process chemical cleaning of hot water boilers, a chemical cleaning scheme is mounted.

The scheme should allow organizing all technological operations necessary for chemical cleaning, namely:

  • preparation of a cleaning solution;
  • filling the boiler with cleaning solution;
  • removal from the washing circuit of air and gases formed during the dissolution of deposits;
  • circulation of washing and neutralizing solutions;
  • neutralization and removal of the wash solution;
  • intensive water washing of all internal surfaces of boilers.

The chemical treatment scheme may include the following equipment:

  • tanks for the preparation and neutralization of the washing solution, are the capacity necessary for the stable operation of the circulation circuit;
  • circulation pumps necessary for filling the boiler, displacing the flushing solution, creating circulation in the flushing circuit;
  • chemical barrel pump - for supplying detergent or neutralizing reagents to the tank when preparing or neutralizing the cleaning solution.
  • connecting hoses, quick-fixing and flange connections, fittings and fittings - for organizing a circulation flushing circuit, filling and emptying the boiler.
  • Figure 1 shows the principle technology system chemical cleaning of the hot water boiler DKVR-10/13.

4. Alkalinization of the boiler.

Alkalinization is used to remove oily, silicic and other contaminants from the internal surfaces of the boiler, as well as some of the loose rust and scale formed during the manufacture, storage and installation of equipment. Cleaning the internal surfaces of the boiler from loose rust, oils and other contaminants is carried out by treating the boiler with a 0.5-0.8% solution of sodium hydroxide with the addition of a 0.3-0.5% solution of trisodium phosphate (alkali) in compliance with the precautionary measures .

As a result of alkalinization, i.e. treatment of the inner surface of the boiler with an alkaline-phosphate solution, occurs:
a) weakening of the adhesion of the layer of rust and scale with the metal due to the penetration of the alkali solution into cracks, its evaporation and partial dissolution of iron oxides with the formation of sodium ferrites;
b) saponification or emulsification of oily contaminants;
c) partial dissolution of silicic impurities with the formation of sodium silicates.

5. Flushing the boiler with technical water.

6. Preparation of the working solution of the reagent and start of the circulation circuit.

Based on the nature of the deposits, the choice and concentration of the reagent is carried out. In the form of reagents, modern highly effective technical detergents based on surfactants, a complex of acids and corrosion inhibitors or hydrochloric acid are used with the introduction of the necessary corrosion inhibitors to protect structural materials.

Technology hydrochemical washing is to ensure the circulation of the washing solution of technical detergent through closed circuit, at a given temperature. During the circulation of the washing solution, a gradual dissolution and removal of layers of accumulated deposits occurs. As the cleaning solution moves through the system, its cleaning power decreases, which is accompanied by an increase in the pH level, this indicates that the solution is reacting with deposits. During washing, the solution is adjusted. The washing solution must be circulated until the pH level does not change, this indicates that the maximum amount of deposits has been removed.

In the process of circulation of the working solution of the washing reagent, it is necessary to carry out chemical control of the cleaning ability of the reagent. Chemical control should be carried out every ½ hour - measurement of the pH of the solution. In the case of an increase in pH to 6, adjust the working solution by adding 10% of initial concentration. The control is carried out with a ph-meter or a litmus indicator.

7. Flushing the boiler with technical water.

After washing with a detergent, the boiler is washed with technical water, and then the internal surfaces of the boiler are passivated.

8. Passivation of internal surfaces of the boiler.

After graduation hydrochemical treatment, flush the circuit with a 0.1-0.2% solution of caustic soda (sodium hydroxide) in order to neutralize and passivate the inner surface of the pipes, then rinse with industrial water to a pH level at the outlet of 6-7. The remains of the unused solution, having a pH level below 6, are neutralized with caustic soda to a pH level of 6-7, then drained into the sewer.

9. Final flushing of the circuit with network water.

During the hydrochemical cleaning of the boiler, the following indicators are monitored:

  • detergent consumption;
  • water consumption during water washings;
  • medium pressure on the pressure and suction pipelines of the pumps, on the discharge pipeline from the boiler;
  • liquid level in the tank;
  • temperature of the working solution of the washing reagent;
  • no accumulation of gas in the boiler circuit.

Our work experience

Over the past years, we have accumulated extensive experience in the field of hydrochemical cleaning of thermal and heat exchange equipment.

Here are some examples of our work and our clients:

  • OAO Mosenergo: participation in the development and implementation of the technology for cleaning boilers PTVM-100 in Zelenograd (article in the Energy Saving magazine, 2000)
  • LLC "Severgazprom" - technical diagnostics of waste heat exchangers and chemical water treatment systems at industrial sites KS-13 Urdoma and KS-16 Yubileiny. In 2000-2006, at Severgazprom LLC, we carried out chemical cleaning of more than 500 waste heat boilers of gas compressor units at 7 compressor stations located in the Komi Republic and the Arkhangelsk Region. In addition, 4 water-heating boilers ABA-4, heat exchangers of 2 central heating stations and heating systems of houses in 2 workers' settlements were cleaned
  • JSC "AvtoVAZ" - development of technology and performance of works for the chemical cleaning of compressed air dryers OSV-250 manufactured by NPP ENSI LLC.
  • MUP "PEUg.Skhodnya" - complex cleaning of 50 shell-and-tube heat exchangers, 10 hot water boilers, commissioning of "Complexon1" systems
  • Sports complex of the Moscow Institute of Electronic Technology - complex cleaning of heat exchangers of systems air heating, heating point, cleaning of water preparation units for the pool
  • NPO ENERGOMASH - cleaning of compressor cooling jackets, test bench heat exchangers and annealing furnaces, shop 429 hot water heat exchangers in the amount of 140 pcs.
  • Moscow Railway - development of technology for in-place cleaning of the cooling system of diesel locomotives together with MIIZhT. (Article in the journal Lokomotiv, 2001)
  • Cleaning of heat exchangers (Alfa Laval, Frolling, Cetheterm, APV, SWEP) for hot water supply and heating and air conditioning, installed in the ITP: Srednerussky Bank of Sberbank of Russia, Financial and Economic Department of the Complex of Perspective Development of the City of Moscow, Bank Credit Swiss First Boston, Svyato-Troitskaya Sergieva Lavra, "New Compound" - English Club, "Don-Stroy", "Atomstroyexport", "DEZ of the Kryukovo District", Central Telegraph, Mostransgaz.

In 2008-2009, we performed cleaning works: 1 Garioni Naval GPT 6000 steam boiler, 2 TVG-4r boilers, 2 KVG 4/115 boilers, 1 KV-GM-35-150 boiler, 1 Ferolli PREX 1250 boiler, 2 boilers PTVM-30, 3 boilers "Turboterm-2000", 12 heat exchangers Alfa laval - Customers - meat processing plant "Partner and K", MUE "Istra heating network", LLC " Heating network Balashikha, CJSC RIDAN, Central Russian Bank of Sberbank of Russia, Holy Trinity Sergius Lavra. An agreement was concluded with the concern "Kurinoe Tsarstvo" (Lipetsk) for the permanent maintenance of boiler houses and ITP for this type of work.

Every cleaning project is different! If you are interested in our services, call us! Specialists will advise you on all issues of their competence, help you choose the best forms of cooperation, calculate the cost of work, and assist in solving existing problems.

Timely chemical flushing of boilers performed by our company's employees will get rid of scale in cases where other cleaning methods do not bring the desired result. The formation of scale on heating surfaces reduces the operating period of the equipment and reduces heat transfer. Maintenance will eliminate the appearance of defects, damage to equipment and system failure.

The effectiveness of the procedure

Chemical flushing of boilers is one of the most popular services, it is regularly performed by the company's masters. Its implementation allows you to clean the surfaces of heat exchangers without dismantling the unit. The reagent used penetrates into hard-to-reach places installations, determining the quality of cleaning.
The choice of solution, reagent concentration and cleaning method is made on an individual basis. It depends on the thickness and density of the coating, the degree of contamination and the material of the internal surfaces of the boiler. The following equipment is required for work: a pump, an expansion tank, a piping system for connecting to a boiler plant and removing carbon dioxide. The procedure requires strict adherence to safety rules due to the use of strong reagents. The execution steps include the following:

  • system diagnostics, determination of the degree of contamination and designation possible defects;
  • selection of one or more solutions for the efficiency and safety of work;
  • flushing (filling liquids and their circulation inside the containers);
  • neutralization of the actions of reagents and passivation of treated surfaces;
  • final rinse with clean water.

As a result of the procedure, the hydraulic performance of the boiler plant is improved, fuel consumption is reduced and efficiency is increased. Metal passivation is the prevention of corrosion formations leading to large-scale destruction of the walls. Cleaning the heat exchanger prevents premature failure and associated financial costs. Regular monitoring of the chemical composition of the water used during the operation of the system will eliminate the problems that occur with excessive mineralization and violation of the acid-base balance.

Treatment Benefits

Performing services for chemical washing boiler equipment, we strive to create attractive conditions for long-term cooperation. Numerous service stations managed to appreciate the responsible attitude to work and the professional level of employees. Benefits of the treatment include:

  • performance of work of any complexity within the time specified in the contract;
  • careful handling of equipment, excluding unintentional breakdowns and damage;
  • compliance with safety standards by masters;
  • absence of factors that contribute to pollution environment;
  • availability of the latest equipment and quality Supplies;
  • an individual approach that determines the choice of reagent, the duration of exposure and the method of manipulation;
  • attractive cost and transparency of pricing policy;
  • providing professional advice and detailed answers to questions regarding the repair and maintenance of boilers of various configurations.

To use the service for chemical washing of boilers, just call the specified phone number or fill out the order form. We are ready to cooperate, contact us!

RUSSIAN JOINT STOCK COMPANY
ENERGY AND ELECTRIFICATION
"UES of RUSSIA"

DEPARTMENT OF SCIENCE AND TECHNOLOGY

STANDARD INSTRUCTIONS
FOR PERFORMANCE CHEMICAL
CLEANING WATER BOILERS

RD 34.37.402-96

ORGRES

Moscow 1997

DevelopedJSC "Firma ORGRES"

PerformersV.P. SEREBRYAKOV, A.Yu. BULAVKO (JSC Firm ORGRES), S.F. SOLOVIEV(CJSC "Rostenergo"), HELL. Efremov, N.I. SHADRINA(JSC "Kotloochistka")

ApprovedDepartment of Science and Technology of RAO "UES of Russia" 04.01.96

Boss A.P. BERSENEV

STANDARD INSTRUCTIONS FOR
OPERATIONAL CHEMICAL
CLEANING WATER BOILERS

RD 34.37.402-96

Expiry date set

from 01.10.97

INTRODUCTION

1. Typical instruction(hereinafter referred to as the Instruction) is intended for personnel of design, installation, commissioning and operating organizations and is the basis for designing schemes and choosing a technology for cleaning hot water boilers at specific facilities and compiling local work instructions (programs).

2. The instruction was drawn up on the basis of the experience gained in carrying out operational chemical cleaning of hot water boilers last years their operation, and determines general order and conditions for the preparation and conduct of operational chemical cleaning of hot water boilers.

The Instruction takes into account the requirements of the following regulatory and technical documents:

Rules for the technical operation of power plants and networks of the Russian Federation (Moscow: SPO ORGRES, 1996);

Standard instructions for operational chemical cleaning of hot water boilers (M.: SPO Soyuztekhenergo, 1980);

Instructions for analytical control during chemical cleaning of thermal power equipment (Moscow: SPO Soyuztekhenergo, 1982);

Guidelines for water treatment and water chemistry regime of water heating equipment and heating networks: RD 34.37.506-88 (M.: Rotaprint VTI, 1988);

Consumption rates of reagents for pre-start and operational chemical cleaning of thermal power equipment of power plants:HP 34-70-068-83(M.: SPO Soyuztekhenergo, 1985);

Guidelines for the use of calcium hydroxide for the preservation of heat and power and other industrial equipment at the facilities of the USSR Ministry of Energy (Moscow: SPO Soyuztekhenergo, 1989).

3. When preparing and carrying out chemical cleaning of boilers, the requirements of the documentation of the equipment manufacturers involved in the cleaning scheme should also be observed.

4. With release of this Instruction the “Standard instruction for operational chemical cleaning of hot water boilers” (M .: SPO Soyuztekhenergo, 1980) is no longer valid.

1. GENERAL PROVISIONS

1.1. During the operation of hot water boilers, deposits form on the internal surfaces of the water path. Subject to the regulated water regime, the deposits consist mainly of iron oxides. In case of violations of the water regime and the use of low-quality water or blowdown water from power boilers for feeding networks, sediments may also contain (in an amount from 5% to 20%) hardness salts (carbonates), silicon compounds, copper, phosphates.

Subject to the water and combustion regimes, the deposits are evenly distributed along the perimeter and height of the screen pipes. A slight increase in them can be observed in the area of ​​the burners, and a decrease in the area of ​​the hearth. With a uniform distribution of heat fluxes, the amount of deposits on the individual pipes of the screens is basically about the same. On pipes of convective surfaces, deposits are also generally evenly distributed along the perimeter of the pipes, and their amount, as a rule, is less than on pipes of screens. However, in contrast to screened convective surfaces on individual pipes, the difference in the amount of deposits can be significant.

1.2. Determination of the amount of deposits formed on the heating surfaces during the operation of the boiler is carried out after each heating season. To do this, pipe samples with a length of at least 0.5 m are cut out from various sections of the heating surfaces. The number of these samples should be sufficient (but not less than 5 - 6 pieces) to assess the actual contamination of the heating surfaces. AT without fail samples are cut out from screen tubes in the area of ​​burners, from top row the upper convective package and the bottom row of the lower convective package. The need to cut an additional number of samples is specified in each individual case, depending on the operating conditions of the boiler. Determination of the specific amount of deposits (g / m 2) can be performed in three ways: by weight loss of the sample after etching it in an inhibited acid solution, by weight loss after cathodic etching, and by weighing the deposits removed mechanically. The most accurate of these methods is cathodic etching.

The chemical composition is determined from an average sample of deposits removed from the surface of the sample mechanically, or from a solution after etching of the samples.

1.3. Operational chemical cleaning is designed to remove deposits from the inner surface of pipes. It should be carried out when the heating surfaces of the boiler are contaminated with 800 - 1000 g / m 2 or more, or with an increase in the hydraulic resistance of the boiler by 1.5 times compared to the hydraulic resistance of a clean boiler.

The decision on the need for chemical cleaning is made by a commission chaired by the chief engineer of the power plant (head of the heating boiler house) based on the results of analyzes for the specific contamination of heating surfaces, determining the condition of the pipe metal, taking into account the boiler operation data.

Chemical cleaning is usually carried out in summer period when the heating season is over. In exceptional cases, it can be carried out in winter, if the safe operation of the boiler is disturbed.

1.4. Chemical cleaning must be carried out using a special installation, including equipment and pipelines that ensure the preparation of flushing and passivating solutions, their pumping through the boiler path, as well as the collection and disposal of waste solutions. Such an installation must be carried out in accordance with the project and linked to the general plant equipment and schemes for the neutralization and neutralization of waste solutions of the power plant.

2. REQUIREMENTS FOR TECHNOLOGY AND CLEANING SCHEME

2.1. Washing solutions should provide high-quality cleaning surfaces, taking into account the composition and amount of deposits present in the boiler screen pipes and to be removed.

2.2. It is necessary to assess the corrosion damage to the pipe metal of the heating surfaces and select the conditions for cleaning with a cleaning solution with the addition of effective inhibitors to reduce pipe metal corrosion during cleaning to acceptable values ​​and limit the appearance of leaks during chemical cleaning of the boiler.

2.3. The cleaning scheme should ensure the efficiency of cleaning the heating surfaces, the completeness of the removal of solutions, sludge and suspension from the boiler. Cleaning of boilers according to the circulation scheme should be carried out with the speeds of movement of the washing solution and water, providing the specified conditions. In this case, the design features of the boiler, the location of convective packs in the boiler water path and the presence of a large number of horizontal pipes small diameter with multiple bends of 90 and 180°.

2.4. It is necessary to carry out neutralization of residual acid solutions and post-flushing passivation of the heating surfaces of the boiler to protect against corrosion when the boiler is idle for 15 to 30 days or subsequent conservation of the boiler.

2.5. At the choice of technology and treatment scheme should take into account environmental requirements and provide for installations and equipment for the neutralization and disposal of waste solutions.

2.6. All technological operations should be carried out, as a rule, when washing solutions are pumped through the water path of the boiler along a closed circuit. The speed of movement of cleaning solutions during cleaning of hot water boilers should be at least 0.1 m/s, which is acceptable, as it ensures uniform distribution of the cleaning agent in the pipes of the heating surfaces and a constant supply of fresh solution to the surface of the pipes. Water washes must be carried out for discharge at speeds of at least 1.0 - 1.5 m/s.

2.7. Waste cleaning solutions and the first portions of water during water washing should be sent to the plant-wide neutralization and neutralization unit. Water is drained into these installations until a pH value of 6.5 - 8.5 is reached at the outlet of the boiler.

2.8. When performing all technological operations (with the exception of the final water washing with network water according to the standard scheme), process water is used. It is permissible to use network water for all operations, if possible.

3. CHOICE OF CLEANING TECHNOLOGY

3.1. For all types of deposits found in hot water boilers, hydrochloric or sulfuric acid, sulfuric acid with ammonium hydrofluoride, sulfamic acid, low molecular weight acid concentrate (NMA) can be used as a washing agent.

The choice of cleaning solution is made depending on the degree of contamination of the boiler heating surfaces to be cleaned, the nature and composition of deposits. To develop a technological regime for cleaning, samples of pipes cut out from the boiler with deposits are processed in laboratory conditions with the selected solution while maintaining the optimal performance of the cleaning solution.

3.2. Hydrochloric acid is mainly used as a detergent. This is due to its high detergent properties, which allow cleaning of any type of deposits from heating surfaces, even with high specific contamination, as well as the lack of a reagent.

Depending on the amount of deposits, cleaning is carried out in one (with contamination up to 1500 g / m 2) or in two stages (with greater contamination) with a solution with a concentration of 4 to 7%.

3.3. Sulfuric acid is used to clean heating surfaces from iron oxide deposits with a calcium content of not more than 10%. In this case, the concentration of sulfuric acid, according to the conditions for ensuring its reliable inhibition during the circulation of the solution in the purification circuit, should be no more than 5%. When the amount of deposits is less than 1000 g/m 2, one stage of acid treatment is sufficient, with contamination up to 1500 g/m 2, two stages are required.

When only vertical pipes (screen heating surfaces) are cleaned, it is acceptable to use the etching method (without circulation) with a solution of sulfuric acid with a concentration of up to 10%. With the amount of deposits up to 1000 g/m 2 one acid stage is required, with more contamination - two stages.

As a washing solution for removing iron oxide (in which calcium is less than 10%) deposits in an amount of not more than 800 - 1000 g / m 2, a mixture of a dilute solution of sulfuric acid (concentration less than 2%) with ammonium hydrofluoride (of the same concentration) can also be recommended. the mixture is characterized by an increased rate of dissolution of deposits compared to sulfuric acid. A feature of this purification method is the need to periodically add sulfuric acid to maintain the pH of the solution at an optimal level of 3.0 - 3.5 and to prevent the formation of Fe hydroxide compounds ( III).

The disadvantages of methods using sulfuric acid include the formation of a large amount of suspension in the cleaning solution during the cleaning process and a lower rate of dissolution of deposits compared to hydrochloric acid.

3.4. If the heating surfaces are contaminated with deposits of carbonate-iron oxide composition in an amount up to 1000 g/m 2, sulfamic acid or NMA concentrate can be used in two stages.

3.5. When using all acids, it is necessary to add corrosion inhibitors to the solution, which protect the boiler metal from corrosion under the conditions of use of this acid (acid concentration, solution temperature, presence of washing solution movement).

For chemical cleaning, as a rule, inhibited hydrochloric acid is used, into which one of the corrosion inhibitors PB-5, KI-1, B -1 (B-2). When preparing a washing solution of this acid, an inhibitor of urotropin or KI-1 must be additionally introduced.

For solutions of sulfuric and sulfamic acids, ammonium hydrofluoride, MNK concentrate, mixtures of catapine or catamine AB with thiourea or thiuram or captax are used.

3.6. If the contamination is above 1500 g/m 2 or if there is more than 10% silicic acid or sulfates in the deposits, it is recommended to perform alkaline treatment before acid treatment or between acid stages. Alkalinization is usually carried out between the acid stages with a solution of caustic soda or a mixture of it with soda ash. Adding 1-2% soda ash to caustic soda increases the effect of loosening and removing sulfate deposits.

In the presence of deposits in the amount of 3000 - 4000 g/m 2 cleaning of heating surfaces may require successive alternation of several acidic and alkaline treatments.

To intensify the removal of solid iron oxide deposits, which are located in the lower layer, and if there are more than 8–10% silicon compounds in the deposits, it is advisable to add fluorine-containing reagents (fluoride, ammonium or sodium hydrofluoride) to the acid solution, added to the acid solution after 3–4 hours after the start of processing.

In all these cases, preference should be given to hydrochloric acid.

3.7. For post-flush passivation of the boiler, in cases where it is necessary, one of the following treatments is used:

a) treatment of the cleaned heating surfaces with 0.3 - 0.5% sodium silicate solution at a solution temperature of 50 - 60 ° C for 3 - 4 hours with the circulation of the solution, which will provide protection against corrosion of the boiler surfaces after draining the solution in wet conditions in for 20 - 25 days and in a dry atmosphere for 30 - 40 days;

b) treatment with a solution of calcium hydroxide in accordance with the guidelines for its use for the conservation of boilers.

4. CLEANING SCHEMES

4.1. The scheme of chemical cleaning of a hot water boiler includes the following elements:

boiler to be cleaned;

a tank designed for the preparation of cleaning solutions and serving at the same time as an intermediate container when organizing the circulation of cleaning solutions in a closed circuit;

flushing pump for mixing solutions in the tank through the recirculation line, supplying the solution to the boiler and maintaining the required flow rate when pumping the solution along a closed circuit, as well as for pumping the spent solution from the tank to the neutralization and neutralization unit;

pipelines that combine the tank, pump, boiler into a single cleaning circuit and ensure the pumping of the solution (water) through closed and open circuits;

neutralization and neutralization unit, where waste cleaning solutions and contaminated water are collected for neutralization and subsequent neutralization;

hydroash removal channels (GZU) or industrial storm sewerage (PLC), where conditionally clear waters(with pH 6.5 - 8.5) when washing the boiler from suspended solids;

tanks for storing liquid reagents (primarily hydrochloric or sulfuric acid) with pumps for supplying these reagents to the purification circuit.

4.2. The rinsing tank is intended for preparation and heating of washing solutions, it is a blending tank and a place for gas outlet from the solution in the circulation circuit during cleaning. The tank must have an anti-corrosion coating, must be equipped with a loading hatch with a grid with a mesh size of 10´ 10 ÷ 15 ´ 15 mm or perforated bottom with holes of the same size, level glass, thermometer sleeve, overflow and drain pipes. The tank must have a fence, a ladder, a device for lifting bulk reagents, and lighting. Pipelines for supplying liquid reagents, steam, water must be connected to the tank. Solutions are heated with steam through a bubbling device located at the bottom of the tank. It is advisable to bring hot water from the heating network (from the return line) into the tank. Process water can be supplied both to the tank and to the suction manifold of the pumps.

The capacity of the tank must be at least 1/3 of the volume of the flush circuit. When determining this value, it is necessary to take into account the capacity of the network water pipelines included in the cleaning circuit, or those that will be filled during this operation. As practice shows, for boilers with a thermal capacity of 100 - 180 Gcal / h, the volume of the tank must be at least 40 - 60 m 3.

For uniform distribution and facilitating the dissolution of bulk reagents, it is advisable to lead a pipeline with a diameter of 50 mm with a rubber hose from the recirculation pipeline into the tank for mixing solutions into the loading hatch.

4.3. The pump intended for pumping the washing solution along the cleaning circuit must provide a speed of at least 0.1 m / s in the pipes of the heating surfaces. The choice of this pump is made according to the formula

Q= (0.15 ÷ 0.2) S 3600,

where Q- pump flow, m 3 / h;

0.15 ÷ 0.2 - the minimum speed of the solution, m/s;

S- area of ​​maximum cross section boiler water path, m 2;

3600 - conversion factor.

For chemical cleaning of hot water boilers with a thermal output of up to 100 Gcal / h, pumps with a flow rate of 350 - 400 m 3 / h can be used, and for cleaning boilers with a thermal output of 180 Gcal / h - 600 - 700 m 3 / h. The pressure of the flushing pumps must not be less than the hydraulic resistance of the flushing circuit at a speed of 0.15 - 0.2 m/s. This speed for most boilers corresponds to a head of no more than 60 m of water. Art. For pumping cleaning solutions, two pumps are installed for pumping acids and alkalis.

4.4. The pipelines intended for organizing the pumping of cleaning solutions in a closed circuit must have diameters not less than the diameters of the suction and pressure nozzles of the washing pumps, respectively, the pipelines for draining waste washing solutions from the cleaning circuit to the neutralization tank may have diameters that are significantly smaller than the diameters of the main pressure-return ( waste) collectors.

The cleaning circuit must provide for the possibility of draining all or most of the cleaning solution into the tank.

The diameter of the pipeline intended for the removal of wash water into the industrial storm channel or the GZU system must take into account the throughput of these lines. The pipelines of the boiler cleaning circuit must be stationary. Their routing must be chosen in such a way that they do not interfere with the maintenance of the main equipment of the boiler during operation. The fittings on these pipelines should be located in accessible places, the routing of the pipelines should ensure their emptying. If there are several boilers at the power plant (heating boiler house), common pressure-return (discharge) collectors are installed, to which pipelines are connected, designed to clean a separate boiler. Shut-off valves must be installed on these pipelines.

4.5. The collection of washing solutions coming from the tank (along the overflow line, drainage line), from the sampler troughs, from pump leaks through stuffing boxes, etc., should be carried out in a pit, from where they are sent to the neutralization unit by a special pumping pump.

4.6. When carrying out acid treatments, fistulas are often formed in the heating surfaces of the boiler and pipelines of the flushing scheme. Violation of the density of the cleaning circuit can occur at the beginning of the acid stage, and the amount of washing solution loss will not allow further operation. To speed up the emptying of the defective section of the heating surface of the boiler and the subsequent safe repair work to eliminate the leak, it is advisable to upper part boiler to supply nitrogen or compressed air. For most boilers, the boiler vents are a convenient connection point.

4.7. The direction of movement of the acid solution in the boiler circuit must take into account the location of the convective surfaces. It is advisable to organize the direction of solution movement in these surfaces from top to bottom, which will facilitate the removal of exfoliated sediment particles from these elements of the boiler.

4.8. The direction of movement of the washing solution in the screen pipes can be any, since with an upward flow at a speed of 0.1 - 0.3 m / s, the smallest suspended particles will pass into the solution, which at these speeds will not be deposited in the coils of convective surfaces when moving from above down. Large sediment particles, for which the movement speed is less than the soaring speed, will accumulate in the lower collectors of the screen panels, therefore, their removal from there must be carried out by intensive water washing at a water speed of at least 1 m/s.

For boilers with convective surfaces are the outlet sections of the water path, it is advisable to organize the flow direction so that they are the first in the direction of the washing solution when pumping along a closed circuit.

The cleaning circuit must be able to change the flow direction to the opposite, for which a jumper must be provided between the pressure and discharge pipelines.

Ensuring the rate of movement of wash water above 1 m/s can be achieved by connecting the boiler to the heating main, while the scheme should provide for pumping water along a closed circuit with a constant removal of wash water from the boiler circuit while simultaneously supplying water to it. The amount of water supplied to the purification circuit must correspond to bandwidth waste channel.

In order to constantly remove gases from individual sections of the water path, the boiler air vents are combined and discharged into the flushing tank.

The connection of the pressure-return (discharge) pipelines to the water path should be made as close as possible to the boiler. To clean the sections of the network water pipeline between the sectional valve and the boiler, it is advisable to use the bypass line of this valve. In this case, the pressure in the water path must be less than in the network water pipeline. In some cases, this line can serve as an additional source of water entering the purification circuit.

4.9. To increase the reliability of the cleaning circuit and greater safety during its maintenance, it must be equipped with steel reinforcement. In order to exclude the overflow of solutions (water) from the pressure pipeline to the return pipeline through the jumper between them, to pass them into the discharge channel or the neutralization tank and to be able to install, if necessary, a plug, the fittings on these pipelines, as well as on the recirculation line to the tank, must be flanged. The principal (general) scheme of the plant for chemical cleaning of boilers is shown in fig. .

4.10. During chemical cleaning of PTVM-30 and PTVM-50 boilers (Fig. ,), the flow area of ​​the water path when using pumps with a feed rate of 350 - 400 m 3 / h provides a solution movement speed of about 0.3 m / s. The sequence of passage of the washing solution through the heating surfaces may coincide with the movement of network water.

When cleaning the boiler PTVM-30 Special attention it is necessary to pay attention to the organization of the removal of gases from the upper collectors of the screen panels, since the direction of the solution movement has multiple changes.

For the PTVM-50 boiler, it is advisable to supply the cleaning solution to the direct network water pipeline, which will allow organizing the direction of its movement in the convective package from top to bottom.

4.11. During chemical cleaning of the KVGM-100 boiler (Fig. ), the pipelines for supplying and returning cleaning solutions are connected to the pipelines of return and direct network water. The movement of the medium is carried out in the following sequence: front screen - two side screens - intermediate screen - two convective beams - two side screens - rear screen. When passing through the water path, the washing flow repeatedly changes the direction of the medium. Therefore, when cleaning this boiler, special attention should be paid to the organization of a constant removal of gases from the upper screen surfaces.

4.12. During the chemical cleaning of the PTVM-100 boiler (Fig. ), the movement of the medium is organized either according to a two- or four-way scheme. When using a two-way scheme, the speed of the medium will be about 0.1 - 0.15 m/s when using pumps with a flow of about 250 m 3 / h. When organizing a two-way movement scheme, the pipelines for supplying and discharging the washing solution are connected to the pipelines of the return and direct network water.

When using a four-way scheme, the speed of the movement of the medium when using pumps of the same supply is doubled. The connection of the pipelines for supplying and discharging the washing solution is organized into bypass pipelines from the front and rear screens. The organization of a four-way scheme requires the installation of a plug on one of these pipelines.

Rice. 1. Scheme of installation for chemical cleaning of the boiler:

1 - flushing tank; 2 - flushing pumps ;

Rice. 2. Scheme of chemical cleaning of the boiler PTVM-30:

1 - rear additional screens; 2 - convective beam; 3 - side screen of the convective shaft; 4 - side screen; 5 - front screens; 6 - rear screens;

Valve closed

Rice. 3. Scheme of chemical cleaning of the boiler PTVM-50 :

1 - right side screen; 2 - upper convective beam; 3 - lower convective beam; 4 - rear screen; 5 - left side screen; 6 - front screen;

Valve closed

Rice. 4. Scheme of chemical cleaning of the boiler KVGM-100 (main mode):

1 - front screen; 2 - side screens; 3 - intermediate screen; 4 - side screen; 5 - rear screen; 6 - convective beams;

Valve closed

Rice. 5. Scheme of chemical cleaning of the boiler PTVM-100:

a - two-way; b - four-way;

1 - left side screen; 2 - rear screen; 3 - convective beam; 4 - right side screen; 5 - front screen;

The movement of the medium when using a two-way scheme corresponds to the direction of movement of water in the water path of the boiler during its operation. When using a four-way scheme, the passage of the heating surfaces with a washing solution is carried out in the following sequence: front screen - convective packages of the front screen - side (front) screens - side (rear) screens - convective packages of the rear screen - rear screen.

The direction of movement can be reversed when changing the purpose of the temporary pipes connected to the boiler bypass pipes.

4.13. During chemical cleaning of the PTVM-180 boiler (Fig. , ), the movement of the medium is organized either according to a two- or four-way scheme. When organizing the pumping of the medium according to a two-way scheme (see Fig. ), the pressure-discharge pipelines are connected to the pipelines of the return and direct network water. With such a scheme, it is preferable to direct the medium in convective packets from top to bottom. To create a movement speed of 0.1 - 0.15 m/s, it is necessary to use a pump with a feed rate of 450 m 3 / h.

When pumping the medium according to a four-way scheme, the use of a pump of such a supply will provide a speed of 0.2 - 0.3 m / s.

The organization of a four-way scheme requires the installation of four plugs on the bypass pipelines from the distributing upper network water collector to the double-light and side screens, as shown in fig. . The connection of pressure and discharge pipelines in this scheme is carried out to the return network water pipeline and to all four bypass pipes, plugged from the return network water chamber. Given that the bypass pipes haveD at 250 mm and for most of its routing - turning sections, connecting pipelines to organize a four-way scheme requires a lot of labor.

When using a four-way scheme, the direction of movement of the medium along the heating surfaces is as follows: the right half of the two-light and side screens - the right half of the convective part - the back screen - the direct network water chamber - the front screen - the left half of the convective part - the left half of the side and two-light screens.

Rice. 6. Scheme of chemical cleaning of the boiler PTVM-180 (two-way scheme):

1 - rear screen; 2 - convective beam; 3 - side screen; 4 - two-light screen; 5 - front screen;

Valve closed

Rice. 7. Scheme of chemical cleaning of the boiler PTVM-180 (four-way scheme):

1 - rear screen; 2- convective beam; 3- side screen; 4 - two-light screen; 5 - front screen ;

4.14. During chemical cleaning of the KVGM-180 boiler (Fig. ), the movement of the medium is organized according to a two-way scheme. The speed of movement of the medium in the heating surfaces at a flow rate of about 500 m 3 /h will be about 0.15 m/s. Pressure-return pipelines are connected to pipelines (chambers) of return and direct network water.

The creation of a four-pass scheme for the movement of the medium in relation to this boiler requires significantly more alterations than for the PTVM-180 boiler, and therefore its use when performing chemical cleaning is impractical.

Rice. 8. Scheme of chemical cleaning of the KVGM-180 boiler:

1 - convective beam; 2 - rear screen; 3- ceiling screen; 4 - intermediate screen; 5 - front screen;

Valve closed

The direction of movement of the medium in the heating surfaces should be organized taking into account the change in the direction of the flow. In acidic and alkaline treatments, it is advisable to direct the movement of the solution in convective packages from the bottom up, since these surfaces will be the first in the circulation loop along a closed loop. When washing with water, it is advisable to periodically reverse the flow movement in convective packs.

4.15. Washing solutions are prepared either in portions in a washing tank with their subsequent pumping into the boiler, or by adding a reagent to the tank while circulating heated water through a closed cleaning circuit. The amount of the prepared solution must correspond to the volume of the cleaning circuit. The amount of solution in the circuit after the organization of pumping in a closed circuit should be minimal and determined necessary level for reliable operation pump, which is ensured by maintaining a minimum level in the tank. This allows you to add acid during processing to maintain the desired concentration or pH. Each of the two methods is acceptable for all acidic solutions. However, when performing purification using a mixture of ammonium hydrofluoride with sulfuric acid, the second method is preferred. The dosage of sulfuric acid in the cleaning circuit is best done in the upper part of the tank. Acid injection can be done either plunger pump supply of 500 - 1000 l / h, or by gravity from a tank installed at a mark above the flushing tank. Corrosion inhibitors for cleaning solution based on hydrochloric or sulfuric acid do not require special dissolution conditions. They are loaded into the tank before acid is introduced into it.

A mixture of corrosion inhibitors used for cleaning solutions of sulfuric and sulfamic acids, a mixture of ammonium hydrofluoride with sulfuric acid and NMA, is prepared in a separate container in small portions and poured into the tank hatch. The installation of a special tank for this purpose is not necessary, since the amount of the prepared mixture of inhibitors is small.

5. TECHNOLOGICAL MODES OF CLEANING

Approximate technological regimes used to clean boilers from various deposits, in accordance with Sec. are given in table. .


Table 1

Type and amount of deposits removed

Technological operation

Solution composition

Technological operation parameters

Note

Reagent concentration, %

Temperature

environment, °С

Duration, h

End Criteria

1. Hydrochloric acid in circulation

With no restrictions

1.1 Water flush

20 and above

1 - 2

1.2. Bucking

NaOH

Na2CO3

1,5 - 2

1,5 - 2

80 - 90

8 - 12

By time

The need for an operation is determined when choosing a cleaning technology depending on the amount and composition of deposits

1.3. Washing with process water

20 and above

2 - 3

The pH value of the discharged solution is 7 - 7.5

1.4. Preparation in the circuit and circulation of the acid solution

Inhibited HCl

Urotropin (or KI-1)

4 - 6

(0,1)

60 - 70

6 - 8

When removing carbonate deposits and reducing the acid concentration, periodically add acid to maintain the concentration of 2 - 3%. When removing iron oxide deposits without acid dosing

1.5. Washing with process water

20 and above

1 - 1,5

Discharge water clarification

When carrying out two or three acid stages, it is allowed to drain the washing solution with a single filling of the boiler with water and drain it

1.6. Re-treatment of the boiler with an acid solution during circulation

Inhibited HCl

Urotropin (or KI-1)

3 - 4

(0,1)

60 - 70

4 - 6

Performed when the amount of deposits is more than 1500 g/m2

1.7. Washing with process water

20 and above

1 - 1,5

Cleaning water clarification, neutral medium

1.8. Neutralization by circulating solution

NaOH (or Na 2 CO 3)

2 - 3

50 - 60

2 - 3

By time

1.9. Drainage of alkaline solution

1.10. Preliminary washing with technical water

20 and above

Discharge water clarification

1.11. Final washing with network water to the heating system

20-80

Carried out immediately before the boiler is put into operation

2. Sulfuric acid in circulation

<10 % при количестве отложений до 1500 г/м 2

2.1. Water flush

20 and above

1 - 2

Discharge water clarification

2.2. Filling the boiler with acid solution and circulating it in the circuit

H2SO4

3 - 5

40 - 50

4 - 6

Stabilization of the iron concentration in the circuit, but not more than 6 hours

Acid free

KI-1 (or catamine)

0,1 (0,25)

Thiuram (or thiourea)

0,05 (0,3)

2.3. Carrying out the operation according to

2.4. Re-treatment of the boiler with acid during circulation

H2SO4

2 - 3

40 - 50

3 - 4

Stabilization of iron concentration

Performed when the amount of deposits is more than 1000 g/m 3

KI-1

Tiuram

0,05

2.5. Performing operations according to paragraphs. 1.7 - 1.11

3. Sulfuric acid pickling

Same

3.1. Water flush

20 and above

1 - 2

Waste water clarification

3.2. Filling the boiler screens with mortar and pickling them

H2SO4

8 - 10

40 - 55

6 - 8

By time

It is possible to use inhibitors: katapina AB 0.25% with thiuram 0.05%. When using less effective inhibitors (1% urotropine or formaldehyde), the temperature should not exceed 45 ° C

KI-1

Thiuram (or thiourea)

0,05

(0,3)

3.3. Carrying out the operation according to

3.4. Re-treatment with acid

H2SO4

4 - 5

40 - 55

4 - 6

By time

Performed when the amount of deposits is more than 1000 g/m2

KI-1

Tiuram

0,05

3.5. Performing the operation according to clause 1.7

3.6. Neutralization by filling the screens with a solution

NaOH (or Na 2 CO 3)

2 - 3

50 - 60

2 - 3

By time

3.7. Drainage of alkaline solution

3.8. Performing the operation according to clause 1.10

It is allowed to fill and drain the boiler two or three times until a neutral reaction

3.9. Performing the operation according to clause 1.11

4. Ammonium hydrofluoride with sulfuric acid in circulation

Iron oxide with calcium content<10 % при количестве отложений не более 1000 г/м 2

4.1. Water flush

20 and above

1 - 2

Discharge water clarification

4.2. Preparation of the solution in the circuit and its circulation

NH4HF2

1,5 - 2

50 - 60

4 - 6

Stabilization of iron concentration

It is possible to use inhibitors: 0.1% OP-10 (OP-7) with 0.02% captax. With an increase in pH over 4.3 - 4.4, additional dosage of sulfuric acid to pH 3 - 3.5

H 2 SO 4

1,5 - 2

KI-1

Thiuram (or Captax)

0,05

(0,02)

4.3. Performing the operation according to clause 1.5

4.4. Re-treatment with cleaning solution

NH4HF2

1 - 2

50 - 60

4 - 6

Stabilization of the iron concentration in the circuit at pH 3.5-4.0

H2SO4

1 - 2

KI-1

Thiuram (or Captax)

0,05 (0,02)

4.5. Performing operations according to paragraphs. 1.7 - 1.11

5. Sulfamic acid in circulation

Carbonate-iron oxide in an amount up to 1000 g / m 2

5.1. Water flush

20 and above

1 - 2

Discharge water clarification

5.2. Filling the circuit with solution and circulating it

Sulfamic acid

3 - 4

70 - 80

4 - 6

Stabilization of hardness or iron concentration in the circuit

No acid overdose. It is desirable to maintain the temperature of the solution by igniting one burner

OP-10 (OP-7)

Captax

0,02

5.3. Performing the operation according to clause 1.5

5.4. Re-treatment with acid similar to paragraph 5.2

5.5. Performing operations according to paragraphs. 1.7 - 1.11

6. NMC concentrate in circulation

Carbonate and carbonate-iron oxide deposits up to 1000 g/m 2

6.1. Water

flushing

20 and above

1 - 2

Discharge water clarification

6.2. Cooking in solution circuit and its circulation

NMC in terms of acetic acid

7 - 10

60 - 80

5 - 7

Stabilization of the iron concentration in the circuit

Acid free

8.3. Performing the operation according to clause 1.5

OP-10 (OP-7)

6.4. Re-treatment with acid similar to paragraph 6.2

6.5. Performing operations according to paragraphs. 1.7 - 1.11

Captax

0,02


Radiation surface of screens, m 2

Surface of convective packages, m 2

Water volume of the boiler, m 3

ptvm -30

128,6

PTVM-50

1110

PTVM-100

2960

PTVM-180

5500

kvgm -30

KVGM-50

1223

KVGM-100

2385

KVGM-180

5520

80 - 100

Data on the surface area of ​​pipes to be cleaned and their water volume for the most common boilers are given in Table. . The actual volume of the cleaning circuit may differ slightly from that indicated in the table. and depends on the length of the return and direct network water pipelines filled with a cleaning solution.

7.5. Consumption of sulfuric acid to obtain a pH value of 2.8 - 3.0 in mixtures with ammonium hydrofluoride is calculated based on the total concentration of the components at their ratio by weight of 1: 1.

From stoichiometric ratios and based on the practice of cleaning, it was found that per 1 kg of iron oxides (in terms of F e 2 O 3) about 2 kg of ammonium hydrofluoride and 2 kg of sulfuric acid are consumed. When cleaning with a solution of 1% ammonium hydrofluoride with 1% sulfuric acid, the concentration of dissolved iron (in terms of F e 2 O 3) can reach 8 - 10 g / l.

8. MEASURES SAFETY COMPLIANCE

8.1. When preparing and carrying out work on the chemical cleaning of hot water boilers, it is necessary to comply with the requirements of the “Safety Rules for the Operation of Thermal Mechanical Equipment of Power Plants and Heating Networks” (M.: SPO ORGRES, 1991).

8.2. Technological operations of chemical cleaning of the boiler begin only after the completion of all preparatory work and the removal of repair and installation personnel from the boiler.

8.3. Before chemical cleaning, all the personnel of the power plant (boiler house) and contractors involved in chemical cleaning are instructed on safety when working with chemical reagents with an entry in the briefing log and the signature of the instructed.

8.4. An area is organized around the boiler to be cleaned, the flushing tank, pumps, pipelines and appropriate warning posters are hung out.

8.5. Enclosing handrails are made on the tanks for the preparation of reagent solutions.

8.6. Good lighting of the cleaned boiler, pumps, fittings, pipelines, stairs, platforms, sampling points and the workplace of the shift on duty is provided.

8.7. Water is supplied by hoses to the reagent preparation unit, to the place of work of personnel for flushing spilled or spilled solutions through leaks.

8.8. Means are provided for neutralizing washing solutions in case of violation of the density of the washing circuit (soda, bleach, etc.).

8.9. The duty shift workplace is provided with a first aid kit with medicines necessary for first aid (individual packages, cotton wool, bandages, tourniquet, boric acid solution, acetic acid solution, soda solution, weak potassium permanganate solution, vaseline, towel).

8.10. It is not allowed to be present in hazardous areas near the equipment to be cleaned and the area where flushing solutions are dumped by persons who are not directly involved in chemical cleaning.

8.11. It is forbidden to carry out hot work near the place of chemical cleaning.

8.12. All work on receiving, transferring, draining acids, alkalis, preparing solutions is carried out in the presence and under the direct supervision of technical managers.

8.13. Personnel directly involved in chemical cleaning work are provided with woolen or canvas suits, rubber boots, rubberized aprons, rubber gloves, goggles, and a respirator.

8.14. Repair work on the boiler, reagent tank is allowed only after their thorough ventilation.

Appendix

CHARACTERISTICS OF REAGENTS USED IN CHEMICAL CLEANING OF WATER BOILERS

1. Hydrochloric acid

Technical hydrochloric acid contains 27 - 32% hydrogen chloride, has a yellowish color and a suffocating odor. Inhibited hydrochloric acid contains 20 - 22% hydrogen chloride and is a liquid from yellow to dark brown (depending on the introduced inhibitor). PB-5, V-1, V-2, katapin, KI-1, etc. are used as inhibitors. The inhibitor content in hydrochloric acid is in the range of 0.5 ÷ 1.2%. The rate of dissolution of steel St 3 in inhibited hydrochloric acid does not exceed 0.2 g/(m 2 h).

The freezing point of a 7.7% hydrochloric acid solution is minus 10 ° C, 21.3% - minus 60 ° C.

Concentrated hydrochloric acid smokes in air, forms a mist, which irritates the upper respiratory tract and the mucous membrane of the eyes. Diluted 3-7% hydrochloric acid does not smoke. The maximum allowable concentration (MPC) of acid vapor in the working area is 5 mg/m 3 .

Skin exposure to hydrochloric acid can cause severe chemical burns. If hydrochloric acid gets on the skin or in the eyes, it must be immediately washed off with a plentiful stream of water, then the affected area of ​​the skin should be treated with 10% sodium bicarbonate solution, and the eyes with 2% sodium bicarbonate solution and contact the first-aid post.

Personal protective equipment: coarse wool suit or acid-resistant cotton suit, rubber boots, acid-resistant rubber gloves, goggles.

Inhibited hydrochloric acid is transported in non-gummed steel rail tank cars, tank trucks, containers. Tanks for long-term storage of inhibited hydrochloric acid should be lined with diabase tiles on acid-resistant silicate putty. The shelf life of inhibited hydrochloric acid in an iron container is not more than one month, after which additional administration of the inhibitor is required.

2. Sulfuric acid

Technical concentrated sulfuric acid has a density of 1.84 g / cm 3 and contains about 98% H 2 SO 4 ; It mixes with water in any proportions with the release of a large amount of heat.

When sulfuric acid is heated, sulfuric anhydride vapors are formed, which, when combined with air water vapor, form an acid fog.

Sulfuric acid, when it comes into contact with the skin, causes severe burns, which are very painful and difficult to treat. When sulfuric acid vapor is inhaled, the mucous membranes of the upper respiratory tract are irritated and cauterized. Contact with sulfuric acid in the eyes threatens with loss of vision.

Personal protective equipment and first aid measures are the same as when working with hydrochloric acid.

Sulfuric acid is transported in steel rail tank cars or tank trucks and stored in steel tanks.

3. Caustic soda

Caustic soda is a white, very hygroscopic substance, highly soluble in water (1070 g / l dissolves at a temperature of 20 ° C). Freezing point of 6.0% solution minus 5° C, 41.8% - 0 ° C. Both solid sodium hydroxide and its concentrated solutions cause severe burns. Contact with alkali in the eyes can lead to serious eye diseases and even loss of vision.

If alkali gets on the skin, it is necessary to remove it with dry cotton wool or pieces of cloth and wash the affected area with a 3% solution of acetic acid or a 2% solution of boric acid. If alkali gets into the eyes, it is necessary to rinse them thoroughly with a stream of water, followed by treatment with a 2% solution of boric acid and contact the first-aid post.

Personal protective equipment: cotton suit, goggles, rubberized apron, rubber gloves, rubber boots.

Caustic soda in solid crystalline form is transported and stored in steel drums. Liquid alkali (40%) is transported and stored in steel tanks.

4. Concentrate and condensate of low molecular weight acids

The purified NMC condensate is a light yellow liquid with the smell of acetic acid and its homologues and contains at least 65% C 1 - C 4 acids (formic, acetic, propionic, butyric). In water condensate, these acids are contained in the range of 15 ÷ 30%.

The purified NMC concentrate is a combustible product with a self-ignition temperature of 425 °C. Foam and acid fire extinguishers, sand, felt mats should be used to extinguish a product on fire.

NMC vapors cause irritation of the mucous membrane of the eyes and respiratory tract. MPC vapors of purified NMC concentrate in the working area 5 mg/m 3 (in terms of acetic acid).

In case of contact with the skin, NMC concentrate and its dilute solutions cause burns. Personal protective equipment and first aid measures are the same as when working with hydrochloric acid, in addition, a brand A gas mask should be used.

Non-inhibited purified NMC concentrate is supplied in railway tanks and steel drums with a capacity of 200 to 400 liters, made of high-alloy steels 12X18H10T, 12X21H5T, 08X22H6T or bimetals (St3 + 12X18H10T, St3 + X17H13M2T), and stored in containers made of the same steel or in tanks made of carbon steel and lined with tiles.

5. Urotropin

Urotropin in its pure form is a colorless hygroscopic crystals. The technical product is a white powder, highly soluble in water (31% at 12° WITH). Easily ignited. In a hydrochloric acid solution, it gradually decomposes into ammonium chloride and formaldehyde. The dehydrated pure product is sometimes referred to as dry alcohol. When working with urotropin, strict compliance with the requirements of fire safety rules is necessary.

If it comes into contact with the skin, urotropine can cause eczema with severe itching, which quickly passes after the cessation of work. Personal protective equipment: goggles, rubber gloves.

Urotropin is supplied in paper bags. Must be stored in a dry place.

6. Wetting agents OP-7 and OP-10

They are neutral yellow oily liquids, highly soluble in water; when shaken with water, they form a stable foam.

If OP-7 or OP-10 gets on the skin, they must be washed off with a stream of water. Personal protective equipment: goggles, rubber gloves, rubberized apron.

Supplied in steel drums and can be stored outdoors.

7. Captax

Captax is a yellow bitter powder with an unpleasant odor, practically insoluble in water. Soluble in alcohol, acetone and alkalis. It is most convenient to dissolve captax in OP-7 or OP-10.

Prolonged exposure to Captax dust causes headache, poor sleep, bitter taste in the mouth. Skin contact may cause dermatitis. Personal protective equipment: respirator, goggles, rubberized apron, rubber gloves or silicone protective cream. At the end of work, it is necessary to thoroughly wash your hands and body, rinse your mouth, shake out overalls.

Captax is supplied in rubber bags with paper and polyethylene liners. Stored in a dry, well-ventilated area.

8. Sulfamic acid

Sulfamic acid is a white crystalline powder, highly soluble in water. When dissolving sulfamic acid at a temperature of 80 ° C and above, its hydrolysis occurs with the formation of sulfuric acid and the release of a large amount of heat.

Personal protective equipment and first aid measures are the same as when working with hydrochloric acid.

9. Sodium silicate

Sodium silicate is a colorless liquid with strong alkaline properties; contains 31 - 32% SiO 2 and 11 - 12% Na 2 O ; density 1.45 g/cm 3 . Sometimes referred to as liquid glass.

Personal protective equipment and first aid measures are the same as when working with caustic soda.

It arrives and is stored in steel tanks. Forms a gel of silicic acid in an acidic environment.



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