Peat - organic soil formed as a result of natural death and incomplete decomposition of marsh plants under conditions high humidity with a lack of oxygen and containing 50% (by mass) or more organic substances. He is the first constituent element genetic series solid fuels(plant, peat, brown coal, coal, anthracite, graphite), formed under the influence of pressure and temperature (Fig. 2.23). Peat formed in reservoirs is underlain by a layer of lacustrine sediments of various thicknesses; peat, formed as a result of swamping due to excessive moisture, lies on a mineral base of various lithological composition. When the process of peat accumulation is interrupted, peat deposits can be covered by other deposits - in these cases, peat is called buried.
Rice. 2.23. Genetic series of solid fuels
Analysis of the organic part of plants revealed the following chemical composition:
48.. .50% carbon, 38...42% oxygen, 6.. .6.5% hydrogen and 0.5...2.3% nitrogen, and in peat-forming plants it is more or less constant. In the process of photosynthesis, complex compounds are formed that are spent on building the body of the plant and nutrition. All these substances are found in plant tissues in different proportions,
A.A. Nitsenko gives the following data: fiber 15 ... 35%, hemicellulose 18 ... 30%, lignin 10 ... 40%, wax, resins, fats up to 10%, insoluble proteins about 5%, minerals (ash) 1 ,5...20% .
Cell membranes of peat-forming plants consist of cellulose, or cellulose-carbohydrate, and hemicellulose close to it. With age, the cell wall becomes impregnated with lignin, which causes the process of lignification. In the cytoplasm of cells there are various inclusions: starch grains, droplets essential oils and resins dissolved in them. The cytoplasm is alkaline. The contents of the vacuoles contain organic acids, which determines its acidic reaction, as well as tannins. In addition, plants contain waxes (stems and leaves of podbel, reed, cranberries), as well as pentosans (nitrogen-containing non-protein substances).
The influence of these substances on the mechanical properties of peat is ambiguous. Cellulose(a polymer consisting of a chain of glucose molecules) provides sufficient tensile strength, bond energy-глюкозидных звеньев 50 ккал/моль, число звеньев в макромолекуле 900-1500, что характеризует высокую реакционную способность. В то же время целлюлоза - наименее устойчивый компонент при биологическом распаде. Hemicellulose differs in smaller weight and the best solubility in alkaline solutions, rather short macromolecular chains. When plants decompose and in the presence of moisture, hemicellulose molecules form associates on the surfaces of cellulose microfibrils and contribute to the strengthening of bonds between cellulose chains. Lignin - a polymer with branched macromolecules linked by hydrogen bonds holds together cellulose fibrils and, together with hemicellulose, determines the strength of plant trunks and stems. This nitrogen-free substance belongs to compounds of the aromatic series; richer in carbon and poorer in oxygen than fiber.
The chemical composition of the organic part of peat is not the same for different groups. When moving from the moss group to the grassy and further to the woody group (Table 2.17), the cellulose content increases, which has a significant effect on the strength and deformation properties of peat soils. in sphagnum moss contains a small amount of bitumen, a lot of easily hydrolyzable and water-soluble compounds of the carbohydrate complex. Mosses have chemical immunity, which allows them to persist for thousands of years. The chemical composition of different types of mosses is very different from each other. Herbal peat formers, compared to mosses and shrubs, contain more cellulose. This causes their lability during humification and leads to the formation of peats with a higher degree of decomposition. Woody peat-forming plants differ from mosses and grasses by a high content of cellulose (more than 50%) and true lignin (non-hydrolyzed residue). The content of bitumen in the wood of conifers and some shrubs reaches 15%, and in hardwoods it is ten times less.
Unlike plants, peat contains a very important group of humic substances, consisting mainly of humic and fulvic acids. Humic acids - infusible dark-colored substances that are part of the organic mass of peat (up to 60%), brown coal (20 ... 40%), soil (up to 10%); their structure has not been definitively established. Ion-exchange, water, thermophysical and strength properties depend on HA. HAs are soluble in alkaline solutions and are widely used as plant growth stimulators, components of drilling compositions, organo-mineral fertilizers, etc. Fulvic acids humic substances soluble in water, acids and alkalis, characterized by a reduced carbon content (up to 40% by weight) and, accordingly, a higher oxygen content. They are more oxidized than other humic substances and impart a brown color to peat waters.
Table 2.17
The chemical composition of the substances of peat-forming plants
Peat-forming plants |
Chemical composition of peat (in % of organic mass) |
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Cellulose |
Hemicellulose |
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sphagnum mosses |
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sheikh cerium |
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Cane |
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heather shrubs |
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Deciduous wood and on |
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Softwood |
The density of solid particles of peat varies from 1.20 to 1.89 g/cm 3 , for normal ash - up to 1.84 g/cm , for peaty soils - up to 2.08 g/cm 3 , the natural density of watered peat differs little and is 1 , 0 ... 1.2 g / cm 3, the density of the peat skeleton is 0.04 G..0.230 g / cm 3. The values \u200b\u200bof the porosity coefficient of peat vary from 6.6 to 37.5 units and more.
When conducting engineering-geological surveys for the classification of peat by variety, it is necessary to establish degree of decomposition of organic matter /),*/, content 1, and ash content D as(Table 2.18). In addition to the mandatory characteristics, the botanical composition should also be determined.
Table 2.18
Classification of organic soils
/. Classification of peat according to the degree of decomposition (34] |
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Variety of peat |
Degradation degree % (or d.u.) |
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slightly decomposed |
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medium decomposed |
20 < Да., <45 |
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badly decomposed |
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2. Classification of peat according to the degree of ash content |
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Variety of peat |
Ash level Dai, units (or %) |
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normal ash |
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high ash |
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3. Classification of peat by botanical composition, type of nutrition and watering of the peat mass |
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Variety |
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Horse |
woody |
It is distinguished by the type of residues of the main peat formers |
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Forest marsh |
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Lowland |
woody |
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Forest marsh |
woody-moss, woody-herbal |
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Herbal, moss, grass-moss |
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Transition |
woody |
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Forest marsh |
woody-moss, woody-herbal |
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Herbal, moss, grass-moss |
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Peat ash content Das, units, - a characteristic expressed by the ratio of the mass of the mineral part of the soil remaining after calcination to the mass of dry peat. In table. 2.19 shows the values of the constitutional ash content (not introduced from the outside) of peat-forming plants. Plant ash consists of the following main elements: silicon, calcium, iron, phosphorus, potassium, magnesium, trace elements (manganese, copper, nickel, etc.) are fixed in the ash in very small quantities. In the plant organs of lowland bogs, the proportion of the mineral part is significantly higher than in the plant organs of raised bogs, with the exception of birch (Table 2.19). The ratios of the organic and mineral parts of marsh plants are different not only for species or groups, but also for different organs of the same plant - the share of the mineral part in the leaves is greater than in the roots and stems.
Determination of the ash content of peat . For determining D as a sample (1...2 g of dry peat) is burned in a muffle furnace, and the residue is calcined at a temperature of 800 ± 25 ° C to a constant weight (with an allowable difference, followed by a weight of up to 0.006 g). When determining the ash content, the difference between two parallel determinations should not be more than 2%.
When using a sample of dry soil, the moisture content is determined in parallel with the burning of peat and then the mass of the wet sample is recalculated for dry. According to the degree of ash content, peat is divided according to Table. 2.18.
Table 2.19
plant type |
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organic matter. % |
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Alder (Alnus glulinosa) |
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Birch (Beiula pubescens) |
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Cane (Phragmites communis) |
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lowland peat |
Sedge rough fruit (Carex iasiocarpa) |
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Sedge peculiar (C. appropinquate) |
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Cotton grass multi-spike (Eriophorum polystachyon) |
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Watch (Menyanthes irifoliata) |
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horsetail (Eq nisei um heleocharis) |
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Drepanocladus vernicosus |
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Sphagnum ohtusum |
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Pine (Pinus silvestris) |
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horse peat |
Podbel (Andromeda polifolia) |
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marsh myrtle (Chamaedaphe calyculata) |
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wild rosemary (ledum palustre) |
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Cotton grass vaginal (Eriophorum vaginatum) |
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sheikh cerium (Scheuchzeria palustris) |
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Sphagnum mageHanicum (Sph. medium) |
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Sph.fuscum |
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sp. angustifoimm |
The content of the mineral component is calculated based on the assumption that the organic mass is completely burnt out during ignition and that the mass is lost only due to the burning of organic matter. Loss on ignition generally refers to the organic matter content of soil containing little or no clay and carbonates. For soils with higher percentages of clay and/or carbonates, most of the loss on ignition may be due to factors unrelated to the organic matter content.
The firing temperature specified in is 800 ± 25 °C, but temperatures up to 440 are recommended in other standards. ± 25 °C. Care must be taken when setting the firing temperature., taking into account the following:
For most applications, an ignition temperature of 500°C or 520°C should be used. Drying and calcination times must be sufficient to ensure equilibrium. If the calcination period is less than 3 hours, the report should indicate that the constancy of mass has been confirmed by repeated weighings.
The degree of decomposition of peat Djp, units, - a characteristic expressed by the ratio of the mass of the structureless (completely decomposed) part, including humic acids and small particles of non-humic plant residues, to the total mass of peat. According to the degree of decomposition DDP peat is subdivided according to the table. 2.18.
Determination of the degree of decomposition of peat . The following physical methods are used in field and laboratory conditions: microscopic, weight, eye-macroscopic and centrifugation, as well as determining the degree of decomposition of peat by its botanical composition (calculation method).
Microscopic method . 50 ... 100 cm * of peat are taken from the sample for analysis, mixed, leveled on a plastic or polyethylene sheet with a layer of 3 ... 5 mm. From the prepared layer with a sampler or a spoon, a portion of peat with a volume of 0.5 cm 3 is collected at 10-12 points, evenly spaced over the area, and placed on a glass slide. In the presence of carbonates in peat, for their destruction, a hydrochloric acid solution with a mass fraction of 10% is dropped onto the selected portion with a pipette. If the peat boils, then process the entire portion placed on a glass slide.
When preparing a peat sample with a moisture content of less than 65% (moisture is the ratio of the mass of water in the soil to the total mass of the soil), a part of the sample is placed in a porcelain bowl (the amount of peat is taken on the basis that, after swelling, the peat will fill the cup by 2 / 3 / d of it volume) and pour a solution of sodium or potassium hydroxide with a mass fraction of 5%. After 24 hours, the peat is thoroughly mixed, the lumps are kneaded, and if it remains lumpy, more of the indicated solution is added and mixed until a homogeneous mushy mass is obtained. With drier peat and to speed up sample preparation, it is crushed in a mortar. About 5 cm * of peat is placed in a porcelain bowl and poured with a solution of sodium or potassium hydroxide with a mass fraction of 5%. The bowl with peat is placed on an electric stove and heated in a fume hood, stirring with a glass rod until hard lumps soften and a homogeneous mushy mass is obtained, then the bowl with peat is cooled to room temperature.
A portion of peat for analysis is taken with a spoon. From each sample, a preparation is prepared on three glass slides. A portion of peat placed on a glass slide is diluted with water to a state of fluidity, thoroughly mixed with needles and distributed over the glass with a thin layer even in thickness. The drug should be so transparent that the whiteness of the paper placed under it at a distance of 50 ... 100 mm shows through it. The dry zone separating the working area of the preparation from the edge of the glass should be about 10 mm wide. The glass slide with the prepared preparation is placed on the microscope stage. The drug is examined at a magnification of 56-140 ", making sure that the particles do not move along the glass. On each slide, ten fields of view are examined by moving it and the area occupied by the structureless part is determined as a percentage relative to the entire area occupied by the drug. Based on the obtained on each glass slide, the values of the degree of decomposition are determined by the arithmetic mean of thirty readings, rounding the result to 5%.The absolute allowable discrepancy between the results of determinations carried out by different performers for one sample should not exceed 10%.
weight method . A portion of 50 g is divided into two equal parts, one of which is dried! in a thermostat at a temperature of 105 ° C and weighed to the second decimal place, and the second is elutriated with a stream of water on a sieve with a hole diameter of 0.25 mm. Elutriation is continued until clear water flows out of the sieve. Remaining on
sieve, the washed plant particles are dried in a thermostat to dryness at 105 °C and weighed. The degree of decomposition is determined by the formula
where a- mass of dry fiber from elutriated sample; b- the same, from an unwashed sample. The conversion of the degree of decomposition determined by the weight method to the degree of decomposition by the microscopic method should be carried out using the graph (Fig. 2.24) in order to classify the soil by variety (Table 2.18.)
Rice. 2.24. Graph for converting the degree of decomposition determined by the gravimetric method to the degree of decomposition by the microscopic method
Eye-macroscopic method. Using table. 2.20, the structural and mechanical properties of peat are evaluated by eye when it is squeezed in the hand and by the color of the water squeezed out of it. The complex of signs of visual determination is supplemented with another indicator - a smear of peat. To do this, an average sample of 0.5 ... 1.0 cm 3 in volume is taken from several places of a peat sample taken from a deposit and placed on a piece of thick paper or on a field diary page. By pressing the index finger on the sample, a horizontal smear of 5 ... 10 cm is made to assess the degree of decomposition.
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Peat - organic fertilizer, is a plant mass decomposed in conditions of excessive moisture and lack of air. The composition of peat includes non-humified plant residues, humus, and mineral compounds.
According to the conditions of formation, peat is divided into three types:
Agrochemical assessment of peat is carried out according to the following properties:
Maximum moisture capacity is a hallmark of high-moor peats. The indicator gradually decreases with the transition to lowland types, but remains quite high.
Agrochemical indicators, % on absolutely dry mass of various types of peat, according to: |
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Peat type |
ash |
pH values |
organic matter |
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mg eq/100g dry weight |
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lowland |
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transition |
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riding |
Peat is widely used in agriculture. In animal husbandry, various types of peat are used for animal bedding. In crop production, peat is used as a component of various composts, in the preparation of peat pots and cubes, as a substrate for greenhouses, as a mulching material, as an independent fertilizer.
Fertilizer brands registered and approved for use in Russia, in the production of which peat is used, are placed in the table on the right.
Peat as a fertilizer is applied on light soils in or.
As a mulching material, surface-ventilated lowland and transitional peat mosses are used.
The drained peatlands are used for crop cultivation. For these purposes, peat extraction is suitable after removing the upper layer of the peat bog with a thickness of the remaining peat layer of at least 50 cm. In this case, liming, the use of various and.
Peat is a combustible mineral, the predecessor of a number of coals, used as a fuel. (a photo)
Deep chemical processing of peat raw materials makes it possible to obtain humic acids, bitumen, methyl and ethyl alcohol, acetic and oxalic acids, furfural, dry ice, fodder yeast, peat coke, semi-coke, and so on.
The introduction of pure peat into the soil is recognized as ineffective. Raw peat contains 80-90% water, and with one ton of it only 100-200 kg of dry matter is added.
Dry peat has a high absorption capacity, and its application leads to the absorption of moisture from the soil. Peat, even at a moisture content of 35-40%, causes the soil to dry out, which, in turn, leads to a slowdown in the decomposition of peat itself, since it does not decompose well in a dry arable layer.
To increase the availability of nitrogen and other nutrients, peat is composted with biologically active components (slurry, feces). For composting, peat is used with a degree of decomposition of more than 20%; lime and ash are added to improve the nutritional qualities of the compost. (a photo)
Peat is used for the preparation of peat-ammonia fertilizers (TMAU) and various peat substrates for greenhouse vegetable growing.
Peat fertilizers and composts have a positive effect on all crops, increasing the quantitative and qualitative characteristics of productivity.
Peat from natural deposits is obtained in various ways. The most modern - milling. The peat deposit is drained using a system of diversion channels, then it is cleared of tree and shrub vegetation and leveled. All peat extraction operations are performed by one specialized combine, the design of which provides for the strengthening of the suction nozzle on the front, and steel cutters on the back.
The cutters destroy the layers of peat, through the nozzles the loosened peat is sucked into the combine and transported to the body with the air flow. Along the way, the peat crumb dries up. From the body on the belt conveyor, it is stored along the edge of the field and subsequently delivered to peat processing plants. (a photo)
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